Normal resting volts on a new quality properly charged battery is 12.9 to 13.1 volts. Your charging was on a old school charger? I recommend a proper maintainer that controls the charging not just dumps 13 to 14 volts at it.
What you see is a over topped off battery that is not a big deal but not ideal. The battery will see these volt levels during normal operation. No real harm done. But if you just used the headlights for a few minutes you would see that number come back down and stay at 12.9 to 13.1 volts.
Voltage is a direct relationship to how much capacity the cells are at in a healthy new battery. 12.0 is dead, 12.5 is half, 13.0 is full 100% but the battery can't be over charged and change the "capacity of power it can hold". The over charge here is just a tiny bit extra that will be used up quick when the battery is used.
I'm not sure what charger you are using but I strongly recommend you go pick up a noco genius charger maintainer.
If you have say a 13.0 volt battery at say 80*f, it can become 12.95v at say 50*f and have the same "charge capacity" all other things being the same.